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What Is Ammonium Bicarbonate in Food?

Feb. 17, 2025

When it comes to traditional baking, few ingredients are as versatile—or as steeped in history—as ammonium bicarbonate. Known by several names such as baking ammonia, hartshorn salt, or simply ammonium carbonate, this white crystalline powder has been a staple in European, Nordic, and Middle Eastern kitchens for centuries. In today's modern food production, ammonium bicarbonate continues to play a key role as a leavening agent, particularly in low-moisture baked goods.


1. Definition & Basic Characteristics


Ammonium bicarbonate (NH₄HCO₃) is an inorganic salt that appears as a white crystalline or powdery substance. Traditionally used as a leavening agent, it's prized for its ability to help baked goods rise. Here's how it works:

Leavening Action:

When heated, ammonium bicarbonate decomposes into carbon dioxide (CO₂), ammonia (NH₃), and water (H₂O). This release of gases causes dough to expand, creating a light, airy structure.

Traditional Names:

You might also hear it referred to as baking ammonia or hartshorn salt—the latter a nod to its historical production from the dry distillation of animal (often deer) antlers.


Ammonium Bicarbonate in Food




2. Applications in Food


Ammonium bicarbonate is most commonly used in low-moisture baked goods such as cookies, crackers, and thin biscuits. Its unique properties make it especially valuable in these applications:

Leavening Effect:

In flat, porous baked goods, ammonium bicarbonate's rapid decomposition during baking releases ample CO₂ and NH₃. The result? A delicate, crisp texture and a beautifully expanded dough.

Scope & Limitations:

Because the ammonia gas must escape during baking, this agent is best suited for items with a high surface area—where gases can readily dissipate. In contrast, high-moisture products like cakes or breads can trap ammonia, potentially imparting an off flavor.


Ammonium Bicarbonate in Food




3. Historical Background & Aliases


The story of ammonium bicarbonate is as fascinating as its function:

A Storied Past:

Long before the advent of modern baking powders, bakers used “hartshorn”—derived from the dry distillation of deer antlers—to leaven their baked goods. This early form of ammonium bicarbonate provided an efficient means of making crisp, light cookies and crackers.

Regional Traditions:

Traditional recipes in regions such as Northern Europe, Germany, Switzerland, and the Nordic countries still call for baking ammonia to achieve a distinctive crispness and delicate flavor profile.




4. Comparison with Other Leavening Agents


Modern baking often relies on ingredients like baking soda or chemical baking powders. So, what makes ammonium bicarbonate stand out?

Gas Production:

Ammonium bicarbonate generates more gas during decomposition than baking soda, which translates to a crisper texture—ideal for cookies and crackers.

Usage & Flavor:

While baking soda is versatile and widely used, it can sometimes leave a soapy or metallic taste if not balanced properly. Ammonium bicarbonate, by contrast, evaporates completely during baking, leaving behind no residual taste—provided it’s used in the right type of recipe.

Substitution Considerations:

When adjusting a recipe, remember that ammonium bicarbonate works best in low-moisture, thin products. For thicker or moister baked items, a blend of leavening agents may be necessary to avoid trapped ammonia and undesirable flavor notes.




5. Safety & Regulations


Safety is paramount in food production, and ammonium bicarbonate has earned its reputation:

Regulatory Status:

Ammonium bicarbonate is classified as GRAS (Generally Recognized As Safe) by the FDA and carries an E number (E503) in the European Union. These designations underscore its long history of safe use in food.

Consumer Concerns:

Some consumers worry about any residual ammonia flavor. However, when used in the correct amount and in suitable recipes, the ammonia gas produced during baking dissipates completely, leaving no off-taste in the final product.




6. Storage & Usage Considerations


To ensure optimal performance, proper handling of ammonium bicarbonate is essential:

Storage:

Because it is sensitive to moisture and can evaporate, ammonium bicarbonate must be stored in airtight containers, away from humidity.

Usage Guidelines:

In food production, careful dosage is key. Our technical experts recommend controlling the amount used based on the product type and baking conditions (temperature and humidity). It’s also important to consider how it interacts with other ingredients in your recipe to achieve the desired texture and flavor.




7. Consumer Perspectives & Common Questions


Consumers often have a few recurring questions about this classic ingredient:


“Why do some traditional cookies use baking ammonia?”

Because it creates a crisper texture without leaving a bitter taste, making it ideal for flat, porous baked goods.


“Is ammonium bicarbonate the same as baking soda?”

Not quite. Although both are leavening agents, ammonium bicarbonate decomposes completely during baking, while baking soda requires an acid to activate and can sometimes leave residual flavors.


“Does it act like yeast?”

No—it is a chemical leavening agent, not a living organism like yeast. Its role is strictly based on chemical decomposition rather than fermentation.


“How does it affect proteins?”

It primarily influences the dough's structure by forming gas bubbles; its impact on proteins is minimal when used appropriately.





Conclusion


Ammonium bicarbonate is a time-tested, versatile ingredient that continues to hold an important place in modern food processing. Its ability to produce a light, crisp texture in cookies, crackers, and other baked goods—without imparting off-flavors—is unmatched by many modern leavening agents. With a rich history, proven safety profile, and specialized applications, it remains an essential tool for traditional and innovative baking alike.


As a global leading chemical distributor, TJCY is committed to providing high-quality ammonium bicarbonate for the food industry, ensuring that customers receive stable, safe, and efficient solutions in food production. For procurement or more information, please contact us.


Email: public@tjcyint.com

Tel.: +86 351 828 1246

Fax: +86 351 820 6170


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